Paleoproterozoic juvenile magmatism within the northeastern sector of the São Francisco paleocontinent: Insights from the shoshonitic high Ba–Sr Montezuma granitoids     

《地学前缘(英文版)》2020,11(5):1821-1840

New,integrated petrographic,mineral chemistry,whole rock geochemical,zircon and titanite UPb geochronology,and zircon Hf isotopic data from the Montezuma granitoids,as well as new geochemical results for its host rocks represented by the Corrego Tingui Complex,provides new insights into the late-to post-collisional evolution of the northeastern Sao Francisco paleocontinent.U-Pb zircon dates from the Montezuma granitoids spread along the Concordia between ca.2.2 Ga to 1.8 Ga and comprise distinct groups.Group I have crystallization ages between ca.2.15 Ga and 2.05 Ga and are interpreted as inherited grains.Group II zircon dates vary from 2.04 Ga to1.9 Ga and corresponds to the crystallization of the Montezuma granitoids,which were constrained at ca.2.03 Ga by the titanite U-Pb age.Inverse age zoning is common within the ca.1.8 Ga Group III zircon ages,being related to fluid isotopic re-setting during the Espinhaco rifiting event.Zircon ε_(Hf)(t) analysis show dominantly positive values for both Group I(-4 to+9) and Ⅱ(-3 to+8) zircons and T_(DM2) model ages of 2.7-2.1 Ga and 2.5-1.95 Ga,respectively.Geochemically,the Montezuma granitoids are weakly peraluminous to metaluminous magnesian granitoids,enriched in LILES and LREE,with high to moderate Mg#and depleted in some of the HFSE.Their lithochemical signature,added to the juvenile signature of both inherited and crystallized zircons,allowed its classification as a shoshonitic high Ba-Sr granitoid related to a late-to post-collisional lithosphere delamination followed by asthenospheric upwelling.In this scenario,the partial melting of the lithospheric mantle interacted with the roots of an accreted juvenile intra-oceanic arc,being these hybrid magma interpreted as the source of the Montezuma granitoids.The Corrego Tingui Complex host rocks are akin to a syn-to late-collisional volcanic arc granitoids originated from the partial melting of ancient crustal rocks.The results presented in this study have revealed the occurrence of juvenile rocks,probably related to an island arc environment,that are exotic in relation to the Paleo-to Neoarchean crust from the Sao Francisco paleocontinent's core.  相似文献   

华北南缘中元古界高山河群碎屑锆石U-Pb年代学及其地质意义^*          下载免费PDF全文

王淼  周洪瑞  张恒 《古地理学报》2020,22(1):39-55

为了探讨华北板块南缘中元古代沉积地层的时代归属和物质来源、区域古地理格局和大地构造特征,对豫西灵宝福地地区的高山河群进行碎屑锆石U-Pb年代学和锆石微量元素特征研究。获得的高山河群年龄最小(年轻)的单颗碎屑锆石 ²⁰⁷Pb/²⁰⁶Pb 年龄值为1685±39 Ma,从而限制了高山河群最早沉积年龄不早于1700 Ma。结合上覆的龙家园组年代学标定(1594±12 Ma),将高山河群的形成年代限定为1700—1600 Ma,即中元古代长城纪的中晚期,属国际地质年表的“固结纪”。高山河群中碎屑锆石 ²⁰⁷Pb/²⁰⁶Pb 年龄范围为1685—2751 Ma,呈现1850 Ma、2150 Ma、2300 Ma和2500 Ma共4个年龄峰值,对应于华北克拉通古元古代重要的地质事件,并且高山河群以1850 Ma和2500 Ma峰值年龄段的地质体为主要的物源区。根据高山河群与云梦山组碎屑锆石年龄频率对比,推测在豫西地区西侧存在以往报道较少的年龄为2500 Ma的地质体。根据熊耳群火山岩及其对应锆石的地球化学特征和熊耳期盆地动力学性质,并结合高山河群沉积相特征和沉积盆地构造属性,认为熊耳群形成于与“岛弧”共生的拉张性质的弧后盆地地区,而其上覆的高山河群为弧后盆地靠近大陆一侧的具有被动大陆边缘性质的滨浅海沉积。  相似文献   

辽北开原地区房木花岗斑岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

豆世勇 《吉林大学学报(地球科学版)》2020,50(6):1752-1765

研究区位于华北克拉通北缘东段、华北克拉通与兴蒙造山带的交接部位。本文通过对辽北开原地区房木花岗斑岩的岩石学、年代学和地球化学研究，探讨了其形成时代、岩石成因和构造环境，并进一步探讨了华北克拉通东部岩石圈减薄的起始时间。用LA-ICP-MS技术测定了花岗斑岩的锆石U-Pb同位素，获得其锆石²⁰⁶Pb/²³⁸U加权平均年龄为（117±1）Ma，表明花岗斑岩形成于早白垩世。花岗斑岩具有高硅、富碱、贫镁和钙的特征，富集大离子亲石元素（K、Rb）和高场强元素（Th、Ta、Nb），亏损Sr、Ba、P、Ti元素，稀土配分曲线均呈现右倾海鸥型，具有明显的负Eu异常；显示研究区花岗斑岩为A型（A₁亚型）花岗岩，形成于古太平洋俯冲的后造山伸展环境，其岩浆源于地幔物质上涌而导致的地壳物质重熔。研究区在（156±1）Ma之前，属于挤压造山环境，表明研究区岩石圈减薄时间应处于156~117 Ma之间。  相似文献   

Barium Isotopic Compositions in Thirty‐Four Geological Reference Materials Analysed by MC‐ICP‐MS     

Ya‐Jun An  Xin Li  Zhao‐Feng Zhang 《Geostandards and Geoanalytical Research》2020,44(1):183-199

Measurement of Ba isotope ratios of widely available reference materials is required for interlaboratory comparison of data. Here, we present new Ba isotope data for thirty‐four geological reference materials, including silicates, carbonates, river/marine sediments and soils. These reference materials (RMs) cover a wide range of compositions, with Ba mass fractions ranging from 6.4 to 1900 µg g^?1, SiO₂ from 0.62% to 90.36% m/m and MgO from 0.08% to 41.03% m/m. Accuracy and precision of our data were assessed by the analyses of duplicate samples and USGS rock RMs. Barium isotopic compositions for all RMs were in agreement with each other within uncertainty. The variation of δ^138/134Ba in these RMs was up to 0.7‰. The shale reference sample, affected by a high degree of chemical weathering, had the highest δ^138/134Ba (0.37 ± 0.03‰), while the stream sediment obtained from a tributary draining carbonate rocks was characterised by the lowest δ^138/134Ba (?0.30 ± 0.05‰). Geochemical RMs play a fundamental role in the high‐precision and accurate determination of Ba isotopic compositions for natural samples with similar matrices. Analyses of these RMs could provide universal comparability for Ba isotope data and enable assessment of accuracy for interlaboratory data.  相似文献   

大兴安岭北段三根河林场新民组流纹岩锆石U－Pb定年及地球化学特征     

李中会  李阳  李睿杰  李凯 《地质与资源》2020,29(4):310-318

三根河林场新民组火山岩主要由流纹岩、流纹质熔结凝灰岩组成，U－Pb定年结果表明流纹岩形成于165.71±0.83 Ma的中侏罗世.岩石地球化学分析结果显示，SiO₂含量71.05%～76.77%，Na₂O+K₂O含量6.66%～8.49%，铝饱和指数（A/CNK）1.02～1.17，相对富硅、碱、过铝质，稀土元素总量中等，轻、重稀土元素分馏明显，具有较强的Eu负异常（δEu=0.39～0.66）和Dy负异常，大离子亲石元素Ba、Sr相对亏损，高场强元素Th、U相对富集，Nb、Dy、Ti相对亏损，岩石具有A型流纹岩的特征.岩石地球化学研究表明，岩浆来源于地壳物质的部分熔融作用.空间上，新民组沿大兴安岭火山岩带中北段均有分布，显示大兴安岭火山岩带于中侏罗世处于张性构造环境.  相似文献   

Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province     

Bo Yang  Alan S. Collins  Grant M. Cox  Amber J. M. Jarrett  Steven Denyszyn  Morgan L. Blades  Juraj Farkaš  Stijn Glorie 《Basin Research》2020,32(6):1734-1750

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.  相似文献   

大兴安岭满归地区变中酸性火山岩LA-ICP-MS锆石U-Pb年龄及其地质意义     

李中会  李睿杰  李阳  沙环宇 《中国地质调查》2020,7(1):47-52

对大兴安岭满归地区新元古界—下寒武统大网子组变中酸性火山岩进行锆石U-Pb同位素年代学研究,探讨其形成时代及地质意义。大网子组由变安山岩、变英安岩、变流纹岩和少量变晶屑凝灰岩组成,缺少板岩、变砂岩、片岩等沉积岩夹层。通过对变安山岩进行锆石U-Pb同位素年龄测定,获得其锆石²⁰⁶Pb/²³⁸U加权平均年龄为(199±1) Ma,表明大网子组变中酸性火山岩形成于早侏罗世早期,非前人认为的形成于新元古代—早寒武世。额尔古纳地块早侏罗世火山岩为漠河盆地提供了物源,表明额尔古纳地块在早侏罗世处于火山-岩浆弧构造背景。该研究为蒙古—鄂霍茨克洋闭合过程中的地球动力学研究提供了新资料。  相似文献   

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

淮南顾桥煤矿新构造运动的证据     

韩必武  韩鹤威  白志钊 《中国煤炭地质》2020,(1):11-17,31

新构造运动系指晚新生代以来的构造运动,其在天然地震研究、煤田地质与油气勘探、城市建设等领域均具有重要的意义。以淮南顾桥煤矿为研究区,结合区域构造背景和顾桥煤矿的地震地质条件,利用地震解释中的层拉平技术恢复研究区典型剖面的古构造地貌,厘定了各条断层的时空配置关系;结合13块钻孔岩心样品的ESR和热释光年龄,定量分析了断层的发育年代。结果表明:研究区存在新构造运动,且与地震层拉平构造演化预测结论吻合;研究成果对于顾桥煤矿的设计和安全生产的意义。  相似文献